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• W2950344513 abstract "The oxycarbonate Sr4Fe2O6CO3 has been revisited, using a new synthesis route. Its microstructure has been established by electron microscopy and evidences an orthorhombic−monoclinic distortion at 220 K. The latter is associated with a spin reorientation (≈7°) visible in magnetic susceptibility, heat capacity, and neutron diffraction studies. To understand the structural transition, particular attention has been paid for the carbonate groups: they adopt a specific orientation within a layer but different in successive layers, which involve disorder along c⃗ and order in the (a,b) plane and are at the origin of the unusual broadening of the Mössbauer lines." @default.
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• W2950344513 date "2004-06-23" @default.
• W2950344513 modified "2023-10-14" @default.
• W2950344513 title "Spin Reorientation Associated with a Structural Transition in the Iron Oxycarbonate Sr₄Fe₂O₆CO₃" @default.
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• W2950344513 doi "https://doi.org/10.1021/cm0401241" @default.
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