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- W2950351189 abstract "Photoinduced oxidation of primary, secondary, and tertiary alcohols by several tungstates of varying structural complexity (WO/sub 2/(OR)/sub 2/, PW/sub 12/O/sub 40//sup 3-/, or (WO/sub 3/)/sub n/) requires strong alcohol precomplexation before photoactivation and occurs via a rapid two-electron transfer, in contrast to previous mechanistic suggestion. The relative efficiencies for alcohol oxidation induced by excitation of a series of heteropolytungstates of increasing molecular complexity are reported. Mechanistic features of the photocatalytic oxidation are described, and a comparison is drawn between thermal and photochemical activation of the heteropolytungstates." @default.
- W2950351189 created "2019-06-27" @default.
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- W2950351189 date "1988-02-09" @default.
- W2950351189 modified "2023-09-25" @default.
- W2950351189 title "ChemInform Abstract: Photoactivation of Metal Oxide Surfaces: Photocatalyzed Oxidation of Alcohols by Heteropolytungstates." @default.
- W2950351189 cites W2075580148 @default.
- W2950351189 doi "https://doi.org/10.1002/chin.198806105" @default.
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