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- W2950358974 abstract "Alkoxo complexes, M(OR)Ln and MH(OR)Ln (M=Co, Rh, Ru; L=PPh3; R=CH(CF3)2, CHPh(CF3)), have beeen prepared by insertion of fluoroketones into M–H bonds in CoH(N2)L3, RhHL4, and RuH2L4. Hydrogenolysis of the Ru- and Rh-alkoxo complexes with H2 or ethanol liberates corresponding fluoroalcohols in good yields. Catalytic activity in hydrogenation of ketones is correlated with the ease of hydrogenolysis of the alkoxo complexes." @default.
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- W2950358974 date "1985-02-19" @default.
- W2950358974 modified "2023-10-18" @default.
- W2950358974 title "ChemInform Abstract: PREPARATION AND PROPERTIES OF GROUP 8 TRANSITION METAL ALKOXIDES RELEVANT TO CATALYTIC HYDROGENATION OF KETONES TO ALCOHOLS" @default.
- W2950358974 cites W2090473951 @default.
- W2950358974 doi "https://doi.org/10.1002/chin.198507136" @default.
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