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- W2950360017 abstract "Highly dispersed Pd(0) nanoparticles were successfully immobilized into stable N-heterocyclic carbene-based microporous organic polymer (NHC-MOP) via a simple post-treatment. The microporous structure of the NHC-MOP polymer can efficiently prevent the aggregation of Pd nanoparticles and the NHC-MOP network embedding with N-heterocyclic carbene ligand can efficiently disperse Pd particles, which promoting the catalytic activity of the polymers. As-synthesized Pd@NHC-MOP catalyst shows excellent catalytic activity in catalyzing the Suzuki-Miyaura and Heck cross-coupling reactions. The superior utility of Pd@NHC-MOP in catalysis was elucidated by the broad scope of the reactants and the high yields of the reaction products, together with the high recyclability of the catalyst. The Pd@NHC-MOP catalyst can be reused at least eleven times for Suzuki-Miyaura coupling reaction or nine times for Heck coupling reaction without any significant loss of the catalytic activity." @default.
- W2950360017 created "2019-06-27" @default.
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- W2950360017 date "2016-09-01" @default.
- W2950360017 modified "2023-09-23" @default.
- W2950360017 title "ChemInform Abstract: N-Heterocyclic Carbene-Based Microporous Organic Polymer Supported Palladium Catalyst for Carbon-Carbon Coupling Reaction." @default.
- W2950360017 cites W2403506587 @default.
- W2950360017 doi "https://doi.org/10.1002/chin.201639050" @default.
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