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- W2950366283 abstract "The reaction of perfluoro-1,2-dichlorocyclobutene with t-butyllithium leads to replacement of Cl by Li. The lithio derivative was stable to −30°C and reaction with trimethylsilyl chloride gave perfluoro-1-chloro-2-trimethylsilylcyclobutene. The reaction of the latter with t-butyllithium leads to dehalogenation and the addition of t-butyl to form a dimeric compound. The reaction of 1-chloro-2,2,3,3-tetrafluorocyclobutene with phenyllithium followed by treatment with deuterium oxide gave perfluoro-1-phenylcyclobutene-2-d1, suggesting that perfluorocyclobutyne may have been an intermediate." @default.
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- W2950366283 date "1997-03-01" @default.
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- W2950366283 title "Reactions of perfluoro-1-chloro-2-trimethylsilylcyclobutene" @default.
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- W2950366283 doi "https://doi.org/10.1016/s0040-4039(97)00190-1" @default.
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