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- W2950366958 abstract "Light blue [Cu(CN)en 2 ]I was prepared by reaction of copper iodide with ethylenediamine (en) and potassium cyanide in acetonitrile in air. It crystallizes in the space group C2 (No. 5) with a = 11.082(6), b = 7.155(2), c = 9.017(3) Å , β = 127.00(3)°, and Z = 2. The structure was refined from 1069 unique reflections and 90 parameters. The refinement converged to R1=0.018 and wR2=0.041 (all reflections). Copper has a trigonal bi-pyramidal environment formed by two en molecules and one CN− anion. The iodine anion shows no direct contact to the Cu 2+ center. The propeller shaped complexes [Cu(CN)en 2 ] + are all oriented parallel in the crystal structure. [Cu(CN)en 2 ] + cations and I − anions form a zincblende related arrangement." @default.
- W2950366958 created "2019-06-27" @default.
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- W2950366958 date "2006-07-01" @default.
- W2950366958 modified "2023-09-25" @default.
- W2950366958 title "[Cu(CN)en2]I – Copper Amine Propellers" @default.
- W2950366958 doi "https://doi.org/10.1515/znb-2006-0701" @default.
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