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W2950369445 endingPage "10" @default.
W2950369445 startingPage "1" @default.
W2950369445 abstract "Abstract Reactions of anhydrous lanthanide trichlorides, LnCl3 (Ln = Ce, Nd, Ho), with 2 equiv. of lithium-cyclopropylethinylamidinates, Li[c-C3H5–C C–C(NR)2] (1a: R = iPr, 1b: R = cyclohexyl (Cy)), afforded a series of new lanthanide-bis(cyclopropylethinylamidinates). In the case of cerium and neodymium, the chloro-bridged dimers [{c-C3H5–C C–C(NR)2}2Ln(μ-Cl)(THF)]2 (2a: Ln = Ce, R = iPr; 2b: Ln = Ce, R = Cy; 2c: Ln = Nd, R = Cy) were isolated, whereas the smaller holmium afforded the “ate” complex [c-C3H5–C C–C(NCy)2]2Ho(μ-Cl)2Li(THF) (OEt2) (3). An initial study showed that these complexes effectively catalyze the addition of aniline derivatives to carbodiimides to give N-arylguanidines. The new complexes 2a–c and 3 as well as the N-arylguanidines o-C6H4(NH2)[-N C(NHiPr)2] (8) and p-C6H4Cl[-N C(NHiPr)2] (9) have been structurally characterized by X-ray diffraction." @default.
W2950369445 created "2019-06-27" @default.
W2950369445 creator A5003403720 @default.
W2950369445 creator A5005752122 @default.
W2950369445 creator A5037534218 @default.
W2950369445 creator A5069558116 @default.
W2950369445 creator A5089476171 @default.
W2950369445 date "2015-06-01" @default.
W2950369445 modified "2023-10-16" @default.
W2950369445 title "Lanthanide(III)-bis(cyclopropylethinylamidinates): Synthesis, structure, and catalytic activity" @default.
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W2950369445 doi "https://doi.org/10.1016/j.jorganchem.2015.01.034" @default.