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- W2950369511 abstract "An investigation of the one-carbon homologation of some 1-tribromomethyl-isoquinoline and 2-tribromomethyl-quinoline derivatives was conducted. Under the influence of an aqueous solution of silver nitrate in the presence of a nucleophilic species (MeOH, H2O, EtNH2), these derivatives led to the respective expanded heterocycles, 2H-1- and 2H-3-benzazepin-2-one derivatives. A mechanism for this novel ring enlargement involving initial formation of an aziridinium, and its subsequent opening to form a stabilized benzylic carbocation, is proposed to explain the results." @default.
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- W2950369511 date "2007-11-01" @default.
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- W2950369511 title "A new enlargement methodology for the preparation of 2H-1- and 2H-3-benzazepin-2-one derivatives" @default.
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- W2950369511 doi "https://doi.org/10.1016/j.tet.2007.08.094" @default.
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