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• W2950373896 abstract "Readily available methyl 3-formylindol-2-ylacetate and N-tosyl-4-chloro-3-piperidone oxime have been used to construct the tetracyclic skeleton of the apparicine class of monoterpene indole alkaloids in only four steps in 80% overall yield. Key transformations in this convergent approach involve use of an intermolecular ester enolate/nitrosoalkene conjugate addition to form the C-15/16 bond, followed by a reductive cyclization to construct the C-ring of the tetracycle." @default.
• W2950373896 created "2019-06-27" @default.
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• W2950373896 date "2014-06-20" @default.
• W2950373896 modified "2023-10-16" @default.
• W2950373896 title "Convergent Approach to the Tetracyclic Core of the Apparicine Class of Indole Alkaloids via a Key Intermolecular Nitrosoalkene Conjugate Addition" @default.
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• W2950373896 doi "https://doi.org/10.1021/jo501067u" @default.
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