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- W2950374695 abstract "Total synthesis of the Lycopodium alkaloid lyconadin A was achieved in 18 steps starting from a readily available vinylogous ester and bromopicoline. The key step in the total synthesis is a proximity-driven oxidative C−N bond-forming reaction that yields the lyconadin pentacycle from a tetracyclic precursor. The key tetracycle, which has been prepared for the first time, is a versatile intermediate that may be utilized for the total synthesis of a variety of Lycopodium alkaloids. Critical to the success of this plan was the efficient preparation of a pyridine-annulated cycloheptadiene tricycle that promises to be a general strategy to access a variety of seven-membered ring containing natural products." @default.
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- W2950374695 date "2008-10-14" @default.
- W2950374695 modified "2023-09-26" @default.
- W2950374695 title "ChemInform Abstract: Unified Strategy for the Synthesis of the “Miscellaneous” Lycopodium Alkaloids: Total Synthesis of (.+-.)-Lyconadin A." @default.
- W2950374695 cites W2052387249 @default.
- W2950374695 doi "https://doi.org/10.1002/chin.200842195" @default.
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