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• W2950376676 abstract "We report here the stereoconvergent formylation of (E/Z)-β-bromo-β-fluorostyrene mixtures with carbon monoxide and sodium formate catalyzed by palladium. Optimization of reaction conditions leads to the corresponding pure (Z)-α-fluorocinnamaldehydes in good yields. The reaction was extended to styrenes bearing electro-attracting or electro-donating groups. The obtained α-fluoroaldehydes were smoothly reduced to the corresponding (Z)-β-fluorocinnamic alcohol by NaBH4. The reaction could be performed on functionalized substrates as demonstrated by the access to the glucoside of β-fluoroconiferyl alcohol, (Z)-β-fluoroconiferin, a strong inhibitor of lignin polymerization." @default.
• W2950376676 created "2019-06-27" @default.
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• W2950376676 date "2011-09-07" @default.
• W2950376676 modified "2023-09-25" @default.
• W2950376676 title "Palladium-Catalyzed Stereoconvergent Formylation of (<i>E</i>/<i>Z</i>)-β-Bromo-β-fluorostyrenes: Straightforward Access to (<i>Z</i>)-α-Fluorocinnamic Aldehydes and (<i>Z</i>)-β-Fluorocinnamic Alcohols" @default.
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• W2950376676 doi "https://doi.org/10.1021/jo200798h" @default.
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