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- W2950376739 abstract "A variety of ethylarenes were converted into the corresponding primary aromatic amides in good yields via treatment with N-bromosuccinimide in the presence of a catalytic amount of 2,2′-azobis(isobutyronitrile) in a mixture of ethyl acetate and water, acetonitrile and water, or chloroform and water, followed by reaction with molecular iodine and aq NH3 in one pot. It was found that aryl α-bromomethyl ketones and/or aryl methyl ketones were formed at the first reaction step and their iodoform-type reaction occurred at the second reaction step to provide primary aromatic amides. The present reaction is a useful and practical transition-metal-free method for the preparation of primary aromatic amides from ethylarenes." @default.
- W2950376739 created "2019-06-27" @default.
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- W2950376739 date "2016-06-01" @default.
- W2950376739 modified "2023-09-27" @default.
- W2950376739 title "ChemInform Abstract: Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I2-Aqueous NH3." @default.
- W2950376739 cites W2276903335 @default.
- W2950376739 doi "https://doi.org/10.1002/chin.201627088" @default.
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