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- W2950377746 abstract "Highly diastereoselective synthesis of enantiopure (S)-(E)-1-haloalk-1-ene-3-amines was achieved by reaction of α-amino aldehydes with trihalomethane promoted by chromium dichloride. The absence of racemization in the halomethylenation reaction was checked by chiral HPLC. A mechanism to explain this transformation is proposed." @default.
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- W2950377746 date "2005-01-01" @default.
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- W2950377746 title "Synthesis of enantiopure (S)-(E)-1-haloalk-1-ene-3-amines with total or very high diastereoselectivity by halomethylenation of α-amino aldehydes promoted by CrCl2" @default.
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- W2950377746 doi "https://doi.org/10.1016/j.tetlet.2004.11.152" @default.
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