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- W2950379516 abstract "Tautomycin molecule was disconnected into 3 retrosynthetic segments, A, B and C, each of which was synthesized in optically active form. First coupling between Segments B and C was achieved between an epoxide and a sulfone carbanion in the presence of BF3·OEt2. This product (Segment B/C) and Segment A were further coupled by Yamaguchi esterification method. Final transformation of the furan ring into the maleic anhydride and removal of the protecting groups completed the total synthesis of (+)-tautomycin." @default.
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- W2950379516 date "1995-09-01" @default.
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- W2950379516 title "Total synthesis of (+)-tautomycin" @default.
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- W2950379516 doi "https://doi.org/10.1016/0040-4039(95)01436-l" @default.
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