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- W2950379738 abstract "Designed synthesis of clusters with face bridging functional organic ligands has paved the way for reactivity studies. Simple multiply bonded substrates of the C=C, C=N, and N=N type have been attached to three metal atoms in bonding modes isoelectronic to the p3-alkine, the p3-vinylidene and the p3-alkylidyne fashion. The interconversions of the bonding modes and the cleavage of the multiple bonds have been investigated. Starting from the simple substrates the combination of organic fragments can form new organic molecules. The interconversions of phosphorus ylides in the ligand sphere of clusters shed some light on possible pathways between C atoms and CO resp. CH2 groups on metal surfaces. Likewise, intermediates which are highly reactive in mononuclear complexes can be trapped as stable" @default.
- W2950379738 created "2019-06-27" @default.
- W2950379738 creator A5006021703 @default.
- W2950379738 date "2010-08-22" @default.
- W2950379738 modified "2023-09-26" @default.
- W2950379738 title "ChemInform Abstract: Ligand Sphere Reactivity of Organometallic Clusters" @default.
- W2950379738 cites W2014642376 @default.
- W2950379738 doi "https://doi.org/10.1002/chin.199141286" @default.
- W2950379738 hasPublicationYear "2010" @default.
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