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- W2950382296 abstract "A novel methodology for the synthesis of highly substituted pyridines based on the palladium-catalyzed enolate α-alkenylation of ketones is presented; the formation of aromatic compounds is a new direction for this catalytic C–C bond forming reaction. In the key step, a protected β-haloalkenylaldehyde participates in α-alkenylation with a ketone to afford a 1,5-dicarbonyl surrogate, which then undergoes cyclization/double elimination to the corresponding pyridine product, all in one pot. The β-haloalkenylaldehyde starting materials can be obtained from the corresponding methylene ketone via Vilsmeier haloformylation. Using this concise route, a variety of highly substituted pyridines were synthesized in three steps from commercially available compounds." @default.
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- W2950382296 date "2015-10-27" @default.
- W2950382296 modified "2023-09-27" @default.
- W2950382296 title "ChemInform Abstract: Modular Synthesis of Highly Substituted Pyridines via Enolate α-Alkenylation." @default.
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- W2950382296 doi "https://doi.org/10.1002/chin.201546168" @default.
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