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- W2950384069 abstract "Aromatic compounds and structures have recently attracted a lot of interest because of their importance in material sciences, the design of molecular devices, metabolism and other biological processes. Although the C-C bond formation is now extensively explored, the accessibility of parent and functionalized aromatics is limited to relatively few examples, especially for high molecular mass polycyclic aromatic hydrocarbons (PAHs). Therefore, this review will concentrate on new developments in the preparation of PAHs in the last decade including pyrolytic approaches to bowl-shaped fullerene fragments and other aromatic compounds, photocyclization and metathesis reactions of stilbenes, [2+2+2] cyclotrimerizations of arynes and alkynes as well as modern Diels-Alder, electrophilic cyclization, and other reactions towards condensed aromatic π-systems. Approaches to symmetrical and unsymmetric (hetero)biaryls as well as other transition metal-catalyzed cyclization reactions will also be discussed briefly. It will be shown that a great variety of synthetic procedures has been developed to prepare PAHs with very interesting molecular structures and/or high efficiency, selectivity, and functionality. The review presents 59 schemes and 318 references." @default.
- W2950384069 created "2019-06-27" @default.
- W2950384069 creator A5006654567 @default.
- W2950384069 creator A5048836127 @default.
- W2950384069 date "2010-06-17" @default.
- W2950384069 modified "2023-09-26" @default.
- W2950384069 title "ChemInform Abstract: Modern Routes to Extended Aromatic Compounds" @default.
- W2950384069 cites W202010591 @default.
- W2950384069 doi "https://doi.org/10.1002/chin.199910323" @default.
- W2950384069 hasPublicationYear "2010" @default.
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