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- W2950387003 abstract "Abstract Several Cu(II) complexes coordinated to imidazole (IMDAH) and benzimidazole (BIMDAH) ligands have been isolated as powdered solids. Compounds prepared are Cu(BIMDAH)4Cl2, Cu(IMDAH)4Cl2, Cu(BIMDAH)2Cl2, Cu(IMDAH)2Cl2 and Cu(BIMDA)2 (BIMDA = deprotonated form of BIMDAH ligand). These compounds have been characterized by elemental analysis, and by diffuse reflectance Fourier Transform and X-ray photoelectron spectroscopy. The results show that Cu(BIMDAH)4Cl2 and Cu(IMDAH)4Cl2 are formed as discrete mononuclear complexes in which the ligands are coordinated in a monodentate fashion. In contrast, the Cu- (BIMDAH)2Cl2 and Cu(IMDAH)2Cl2 complexes are formed as polymeric species. The Cu(BIMDA)2 complex also forms a polymeric structure with the ligands coordinated in a bidentate manner. X-ray photoelectron data illustrates that the surface composition of each of these complexes closely resembles that of the bulk material." @default.
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- W2950387003 date "1988-09-06" @default.
- W2950387003 modified "2023-09-26" @default.
- W2950387003 title "ChemInform Abstract: FT-IR and XPS Study of Copper(II) Complexes of Imidazole and Benzimidazole." @default.
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- W2950387003 doi "https://doi.org/10.1002/chin.198836307" @default.
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