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• W2950388078 abstract "Abstract Three new Co(II) coordination polymers based on a flexible ligand 5-(3-carboxybenzyloxy)-isophthalic acid (H3L) namely [Co3(L)2(H2O)4]n·2nDMF (1) (DMF = N,N-dimethylformamide), [Co3(L)2(DMA)2(H2O)2]n·2nDMA (2) (DMA = N,N-dimethylacetamide) and [Co3(L)2(py)2(NMP)(H2O)]n·nNMP·nH2O (3) (NMP = N-methyl-2-pyrrolidone) have been assembled using different solvent. The different size of solvent molecular can affect the structure of the compounds. Interestingly, three compounds all constructed by the same trinuclear unit of [Co3O12] to exhibit two-dimension architecture with kgd topology. In this building block, there are coordinated water and molecules having the carbonyl group as terminal ligands coordinated with cobalt ions, providing a good example for studying the coordinated solvent exchange. When coordinated solvent molecules were replaced by pyridine molecules, which made two Co ions in asymmetric coordination. This symmetry breaking might the reason for compound 3 crystallizes in the noncentrosymmetric space group. Also, magnetic investigation on compound 1 indicates antiferromagnetic coupling exchange interactions between Co(II) ions in the trinuclear cluster unit." @default.
• W2950388078 created "2019-06-27" @default.
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• W2950388078 date "2019-09-01" @default.
• W2950388078 modified "2023-10-14" @default.
• W2950388078 title "Solvent-induced structural transformations of two-dimensional coordination polymers based on trinuclear cobalt unit" @default.
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• W2950388078 doi "https://doi.org/10.1016/j.poly.2019.06.022" @default.
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