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- W2950405792 abstract "An alkali-metal sulfur reactive flux has been used to synthesize a series of quaternary rare-earth metal compounds. These include KLaP(2)S(6) (I), K(2)La(P(2)S(6))(1/2)(PS(4)) (II), K(3)La(PS(4))(2) (III), K(4)La(0.67)(PS(4))(2) (IV), K(9-x)La(1+x/3)(PS(4))(4) (x = 0.5) (V), K(4)Eu(PS(4))(2) (VI), and KEuPS(4) (VII). Compound I crystallizes in the monoclinic space group P2(1)/c with the cell parameters a = 11.963(12) A, b = 7.525(10) A, c = 11.389(14) A, beta = 109.88(4) degrees, and Z = 4. Compound II crystallizes in the monoclinic space group P2(1)/n with a = 9.066(6) A, b = 6.793(3) A, c = 20.112(7) A, beta = 97.54(3) degrees, and Z = 4. Compound III crystallizes in the monoclinic space group P2(1)/c with a= 9.141(2) A, b = 17.056(4) A, c = 9.470(2) A, beta = 90.29(2) degrees, and Z = 4. Compound IV crystallizes in the orthorhombic space group Ibam with a = 18.202(2) A, b = 8.7596(7) A, c = 9.7699(8) A, and Z = 4. Compound V crystallizes in the orthorhombic space group Ccca with a = 17.529(9) A, b = 36.43(3) A, c = 9.782(4) A, and Z = 8. Compound VI crystallizes in the orthorhombic space group Ibam with a = 18.29(5) A, b = 8.81(2) A, c= 9.741(10) A, and Z = 4. Compound VII crystallizes in the orthorhombic space group Pnma with a = 16.782(2) A, b = 6.6141(6) A, c = 6.5142(6) A, and Z = 4. The sulfur compounds are in most cases isostructural to their selenium counterparts. By controlling experimental conditions, these structures can be placed in quasi-quaternary phase diagrams, which show the reaction conditions necessary to obtain a particular thiophosphate anionic unit in the crystalline product. These structures have been characterized by Raman and IR spectroscopy and UV-vis diffuse reflectance optical band gap analysis." @default.
- W2950405792 created "2019-06-27" @default.
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- W2950405792 date "2001-05-10" @default.
- W2950405792 modified "2023-09-30" @default.
- W2950405792 title "Thiophosphate Phase Diagrams Developed in Conjunction with the Synthesis of the New Compounds KLaP<sub>2</sub>S<sub>6</sub>, K<sub>2</sub>La(P<sub>2</sub>S<sub>6</sub>)<sub>1/2</sub>(PS<sub>4</sub>), K<sub>3</sub>La(PS<sub>4</sub>)<sub>2</sub>, K<sub>4</sub>La<sub>0.67</sub>(PS<sub>4</sub>)<sub>2</sub>, K<sub>9-</sub><i><sub>x</sub></i>La<sub>1+</sub><i><sub>x</sub></i><sub>/3</sub>(PS<sub>4</sub>)<sub>4</sub> (<i>x</i> = 0.5), K<sub>4</sub>Eu(PS<sub>4</sub>)<sub>2</sub>, and KEuPS<sub>4</sub>" @default.
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- W2950405792 doi "https://doi.org/10.1021/ic000596r" @default.
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