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- W2950407964 abstract "Abstract 2-Trimethylsilyl-1-oxa-1,3-butadiene (7) reacts with Fe2(CO)9 to form an unstable tetracarbonyliron(0) complex (8) whereas 2-trimethylsilyl-4-phenyl-1-oxa- 1-oxa-1,3-butadiene (9) and 2-(tert-butyldimethylsilyl)-4-phenyl-1-oxa-1,3-butadiene (20) react with Fe2(CO)9 to form highly stable crystalline tricarbonyliron(0) complexes (16 and (21). Complexes (16) and (21) both undergo acylation when reacted with methyl lithium under nitrogen to form γ-ketoacylsilanes [(18) and (22)], but only complex (21) reacts with methyl lithium under carbon monoxide to give the tricarbonyl(vinylketene)iron(0) complex (23)." @default.
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- W2950407964 date "1992-09-01" @default.
- W2950407964 modified "2023-09-27" @default.
- W2950407964 title "Synthesis and reactivity of iron carbonyl complexes of α,β-unsaturated acyl silanes" @default.
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- W2950407964 doi "https://doi.org/10.1016/s0040-4020(01)90375-8" @default.
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