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- W2950409177 abstract "Abstract The metal-catalyzed borylation of alkenes, alkynes, and organic electrophiles with BB compounds was developed for the synthesis of organoboronic esters from simple organic substrates. The platinum(0)-catalyzed addition of bis(pinacolato)diboron to alkenes and alkynes stereoselectively yielded cis -bis(boryl)alkanes or cis -bis(boryl)alkenes. The addition of diboron to 1,3-dienes with a platinum(0) complex afforded a new access to the cis -1,4-bis(boryl)butene derivatives which are a versatile reagent for diastereoselective allylboration of carbonyl compounds. The cross-coupling reaction of diborons with aryl and vinyl halides or triflates, and allyl chlorides or acetates was found to yield aryl-, vinyl-, and allylboronates in high yields in the presence of a base and a palladium catalyst, which provides the first one-step procedure for the synthesis of organoboronic esters from organic electrophiles. The mechanisms and the synthetic applications of these reactions are discussed." @default.
- W2950409177 created "2019-06-27" @default.
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- W2950409177 date "2000-12-26" @default.
- W2950409177 modified "2023-09-26" @default.
- W2950409177 title "ChemInform Abstract: Chemistry of Group 13 Element-Transition Metal Linkage - The Platinum- and Palladium-Catalyzed Reactions of (Alkoxo)diborons" @default.
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- W2950409177 doi "https://doi.org/10.1002/chin.200052270" @default.
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