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- W2950409829 abstract "A flexible diastereo- and enantioselective synthesis of various 1,2-anti tert-butylsulfanyl amines 5a-e is described. As starting material SAMP-hydrazone (S)-2 was obtained from 2-(bromomethyl)-1,3-dioxolane (1) in a three-step procedure. α-Alkylation with various electrophiles, followed by 1,2-addition to the C-N double bond and removal of the auxiliary by cleavage of the N-N-bond results in the title compounds in excellent diastereomeric and enantiomeric excesses (de, ee ≥ 96%)." @default.
- W2950409829 created "2019-06-27" @default.
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- W2950409829 date "2002-01-01" @default.
- W2950409829 modified "2023-09-28" @default.
- W2950409829 title "A Flexible Asymmetric Synthesis of 1,2-anti tert-Butylsulfanyl Amines" @default.
- W2950409829 doi "https://doi.org/10.1055/s-2002-20477" @default.
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