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- W2950416718 abstract "Abstract Candida antarctica lipase catalyzes the selective monoammonolysis and aminolysis of dimethyl succinate with ammonia and aliphatic amines, respectively, in dioxane as solvent. This enzyme shows a high enatioselectivity when racemic amines are used. Optically active amidoesters are also obtained in the reaction of dimethyl succinate with racemic α-methylalkylamines in hexane as solvent. In this medium, the enzyme catalyzes the formation of N-alkylsuccinimides or optically active N-alkyl-α-methylsuccinimides from dimethyl succinate or α-methylsuccinate and amines." @default.
- W2950416718 created "2019-06-27" @default.
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- W2950416718 date "2010-08-17" @default.
- W2950416718 modified "2023-09-27" @default.
- W2950416718 title "ChemInform Abstract: Selective Ammonolysis and Aminolysis of Dimethyl Succinate. Synthesis of Optically Active N-Alkylsuccinimides." @default.
- W2950416718 cites W1970695365 @default.
- W2950416718 doi "https://doi.org/10.1002/chin.199528036" @default.
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