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• W2950420897 abstract "Novel open-framework alkali metal uranyl periodates, having the formula A[(UO2)3(HIO6)(OH)(O)(H2O)].1.5H2O (A = Li, Na, K, Rb, Cs), have been prepared through mild hydrothermal synthesis. These isostructural compounds contain distorted UO7 pentagonal bipyramids that are linked through a uranyl (UO22+) to uranyl cation-cation interaction. This interaction arises from a single axial uranyl oxygen coordinating at an equatorial site of an adjacent uranyl unit. These uranium oxide polyhedra are further bound by IO6 distorted octahedra creating an open-framework structure whose channels contain the alkali metal cations." @default.
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• W2950420897 date "2004-02-14" @default.
• W2950420897 modified "2023-10-17" @default.
• W2950420897 title "Cation−Cation Interactions between Uranyl Cations in a Polar Open-Framework Uranyl Periodate" @default.
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• W2950420897 doi "https://doi.org/10.1021/ja031695h" @default.
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