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- W2950432886 abstract "Abstract The unprecedented base-initiated generation of a nitrobenzyne and subsequent addition of preformed arylacetonitrile anion nucleophiles is reported. In all cases, 2-amino-5-nitro-3-benzo[b]furans are obtained as major product with small amounts of 3-arylmethyl-2-cyano-4-nitrophenols. A mechanism involving ring closure of phenoxide and nitrile groups of the initial aryne-nitrile anion adduct is proposed to account for the formation of the benzofurans. The three isomeric chloronitrobenzynes, however, do not give aryne products when treated with LDA, but rather are reduced to the corresponding bis-dichloroazoxybenzenes." @default.
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- W2950432886 date "2010-06-16" @default.
- W2950432886 modified "2023-09-24" @default.
- W2950432886 title "ChemInform Abstract: The Reaction of 2-Chloro-4-nitrophenol and the Isomeric Chloronitrobenzenes with LDA under Aryne-Forming Conditions." @default.
- W2950432886 cites W1969302098 @default.
- W2950432886 doi "https://doi.org/10.1002/chin.199917055" @default.
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