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- W2950446911 abstract "The synthesis of various substituted fluoren-9-ones has been accomplished by the palladium-catalyzed cyclocarbonylation of o-halobiaryls. The cyclocarbonylation of 4'-substituted 2-iodobiphenyls produces very high yields of 2-substituted fluoren-9-ones bearing either electron-donating or electron-withdrawing substituents. 3'-Substituted 2-iodobiphenyls afford 3-substituted fluoren-9-ones in excellent yields with good regioselectivity. This chemistry has been successfully extended to polycyclic fluorenones and fluorenones containing fused isoquinoline, indole, pyrrole, thiophene, benzothiophene, and benzofuran rings." @default.
- W2950446911 created "2019-06-27" @default.
- W2950446911 creator A5021011699 @default.
- W2950446911 creator A5061187623 @default.
- W2950446911 date "2002-07-04" @default.
- W2950446911 modified "2023-10-18" @default.
- W2950446911 title "Synthesis of Fluoren-9-ones by the Palladium-Catalyzed Cyclocarbonylation of <i>o</i>-Halobiaryls" @default.
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- W2950446911 doi "https://doi.org/10.1021/jo020140m" @default.
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