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- W2950447225 abstract "Abstract The reaction between Ce(IV) and Hg22+ in 1 M (M=mol dm−3) HClO4 at 25 °C has been shown to be catalysed by light, glass and metallic mercury. The kinetics were therefore studied in Teflon vessels in the dark. The addition of Hg2+ ions to mercury(I) stock solutions avoided the formation of colloidal mercury through the disproportionation of Hg22+. When these precautions were taken, the reaction was found to be much slower than reported by previous workers. The rate was first order in Ce(IV) but zero order in Hg(I), and the activation energy was 125 kJ mol−1." @default.
- W2950447225 created "2019-06-27" @default.
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- W2950447225 date "1991-06-01" @default.
- W2950447225 modified "2023-09-27" @default.
- W2950447225 title "Kinetics of the homogeneous reaction between cerium(IV) and mercury(I) ions in aqueous perchloric acid" @default.
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- W2950447225 doi "https://doi.org/10.1016/s0020-1693(00)83045-5" @default.
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