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- W2950453154 abstract "Abstract The syntheses and characteristic physical and chemical properties of representative members of important types of cyclopentadienyl nitrosyl complexes of the Group 6 elements are reviewed. These organometallic compounds contain either 14-valence-electron (14e) Cp′M(NO) or 17e Cp′M(NO) 2 core fragments [Cp′ = an η 5 -cyclopentadienyl ligand, most often η 5 -C 5 H 5 (Cp) or η 5 -C 5 Me 5 (Cp*); M = Cr, Mo, or W]. All the complexes originate from Cp′M(NO)(CO) 2 which can be readily converted into the precursor complexes Cp′M(NO) 2 X, Cp′M(NO)X 2 (M = Mo, W; X = halide) and [Cp′Cr(NO)I] 2 . The latter compounds are convenient starting materials for the synthesis of [CpCr(NO) 2 ] 2 dimer, [CpM(NO) 2 ] + cations, and neutral compounds such as 17e Cp′Cr(NO)(L)(X) (L = Lewis base; X = halide or alkyl), 18e Cp′M(NO)L 2 (L = Lewis base), and 16e or 18e Cp′M(NO)(R)(R′) (M = Mo, W; R, R′ = hydrocarbyl or H). Consideration of the distinctive chemical properties of these compounds has been restricted to transformations in which the Cp′M(NO) and Cp′M(NO) 2 scaffolds are retained. The synthetic utility of these types of cyclopentadienyl nitrosyl complexes of the Group 6 elements for mediating specific organic transformations is also highlighted throughout this review." @default.
- W2950453154 created "2019-06-27" @default.
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- W2950453154 date "2016-02-01" @default.
- W2950453154 modified "2023-09-27" @default.
- W2950453154 title "ChemInform Abstract: The Rich and Varied Chemistry of Group 6 Cyclopentadienyl Nitrosyl Complexes" @default.
- W2950453154 cites W2220819733 @default.
- W2950453154 doi "https://doi.org/10.1002/chin.201610234" @default.
- W2950453154 hasPublicationYear "2016" @default.
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