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- W2950460115 abstract "Abstract The reaction of [Ni(cod)2] (cod = 1,5-cyclooctadiene) with 2-MeC3H4Cl (2- methylallyl chloride), in the presence of different phosphine ligands, has been investigated. PMe3 furnishes the 16-electron allyl species [Ni(η3 -2-MeC3H4) Cl(PMe3)] (1), while dmpe (dmpe = Me2PCH2CH2PMe2) provides an 18-electron, five-coordinate complex, [Ni(η3-2- MeC3H4)Cl(dmpe)] (2). By contrast, the diphosphines Ph2PCH2PPh2 (dppm) and Me2 PCH2PMe2 (dmpm) form the binuclear complexes [[Ni(η3 -2-MeC3H4)Cl]2(μ-R2PCH2PR2)] (R = Ph, 3; Me, 4) containing bridging phosphine ligands. Alkylation of the chloride complex 1 with various Grignard reagents, Mg(R)Cl, allows the isolation of the alkyl-allyl derivatives [Ni(η3-2-MeC3H4)R(PMe3)] (R = CH2SiMe3, 5; CH2CMe3, 6; CH2C6H4-o- Me, 7). The new compounds have been characterized by analytical and spectroscopic techniques (IR, 1H, 13C and 31P NMR)." @default.
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- W2950460115 date "1990-07-03" @default.
- W2950460115 modified "2023-10-03" @default.
- W2950460115 title "ChemInform Abstract: η3-2-Methylallyl Phosphine Complexes of Nickel(II)." @default.
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- W2950460115 doi "https://doi.org/10.1002/chin.199027293" @default.
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