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- W2950461328 abstract "Abstract A concise enantioselective synthesis of A/B bicyclic segment of naturally occurring α-pyrone meroterpenoid pyripyropene A is achieved in 9 steps (LLS) and 7.5% yield starting from R-(−)-carvone. The significant points of the synthesis include: (1) an intramolecular 1, 3-dipolar cycloaddition reaction to construct the A ring and assemble C4 quaternary carbon stereocenter as well; (2) reductive cleavage of the oxazole motif utilized Raney Ni/B(OCH3)3." @default.
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- W2950461328 date "2019-07-01" @default.
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- W2950461328 title "Concise formal synthesis of (+)-pyripyropene A" @default.
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- W2950461328 doi "https://doi.org/10.1016/j.tet.2019.06.017" @default.
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