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- W2950461687 abstract "Molecular self-assembly has been regarded as a promising strategy for the construction of chiral sensing devices. Here, (1R,2R)-N,N-didodecylcyclohexane-1,2-dicarboxamide (DDC) was synthesized and then self-assembled in alcohol, and a chiral helical structure could be formed owing to the intermolecular hydrogen bond and the polarity effect of solvent. The chirality of the resultant helical self-assembly was confirmed by circular dichroism (CD) spectra, and then the chiral helical self-assembly was used for electrochemical recognition of tryptophan (Trp) enantiomers. Due to the higher affinity of the self-assembly toward L-Trp than D-Trp, which was revealed by hydrophilicity evaluation, efficient recognition of the Trp enantiomers (IL-Trp/ID-Trp = 8.74) was achieved." @default.
- W2950461687 created "2019-06-27" @default.
- W2950461687 creator A5017751936 @default.
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- W2950461687 date "2019-07-01" @default.
- W2950461687 modified "2023-10-14" @default.
- W2950461687 title "A chiral helical self-assembly for electrochemical recognition of tryptophan enantiomers" @default.
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- W2950461687 doi "https://doi.org/10.1016/j.elecom.2019.06.004" @default.
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