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- W2950462757 abstract "An efficient and room-temperature procedure is developed for high yield synthesis of novel α,β-unsaturated derivatives of thiopyran 3 directly from ketone 1 and various aldehydes in the presence of catalytic quantities of TMSNMe2 and MgBr2˙OEt2 under solvent-free conditions. The main advantage of the procedure is that the formation of the undesired bis by-products is minimized. In addition, the procedure is applicable to other enolizable carbocyclic and acyclic ketones." @default.
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- W2950462757 date "2011-10-20" @default.
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- W2950462757 title "An Efficient Procedure for the Synthesis of α,β-Unsaturated Ketones and Its Application to Heterocyclic Systems" @default.
- W2950462757 doi "https://doi.org/10.1055/s-0031-1289571" @default.
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