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• W2950467314 abstract "A three-step convergent synthesis of an immunostimulatory oxylipin was developed using an olefin cross metathesis approach. The alkene fragments were prepared in two steps from commercially available starting materials with high stereoselectivity. In particular, an organocatalytic aldehyde α-oxygenation gave high enantioselectivity and yield using as little as 2 mol% catalyst. This synthesis represents the shortest synthesis of any natural product containing the 3-ene-1,2,5-triol moiety and delivers an immunostimulatory oxylipin in 33% overall yield." @default.
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• W2950467314 date "2019-07-01" @default.
• W2950467314 modified "2023-10-16" @default.
• W2950467314 title "Three-step synthesis of oxylipins from D. loretense" @default.
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• W2950467314 doi "https://doi.org/10.1016/j.tetlet.2019.06.040" @default.
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