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- W2950470563 abstract "The efficient construction of the axial chirality of allenes bearing a carbohydrate unit is challenging. Here we observed that the newly developed CuBr2 catalysis may smoothly catalyze the highly diastereoselective three-component reaction of carbohydrates bearing a terminal alkyne unit, aliphatic or aromatic aldehydes, and (R) or (S)-α,α-diphenylprolinol, affording carbohydrates bearing the chiral 1,3-substituted allene entity in very high de (94–99%). Synthetically attractive functionalities, such as hydroxyl, amide, malonate, and even tosylate, etc. could all be well tolerated. The role of the carbohydrate unit has been explored." @default.
- W2950470563 created "2019-06-27" @default.
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- W2950470563 date "2015-12-01" @default.
- W2950470563 modified "2023-09-23" @default.
- W2950470563 title "ChemInform Abstract: A Concise Construction of Carbohydrate-Tethered Axially Chiral Allenes via Copper Catalysis." @default.
- W2950470563 cites W1890117876 @default.
- W2950470563 doi "https://doi.org/10.1002/chin.201551065" @default.
- W2950470563 hasPublicationYear "2015" @default.
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