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- W2950470776 abstract "The difunctional substrate 2,4-dibromothiazole 2 was transformed into the title compounds 1 by consecutive Pd(0)-catalyzed cross-coupling reactions. Aryl zinc reagents which were prepared by ortho-lithiation of compounds 3 and subsequent transmetalation were used as carbon nucleophiles in the first coupling reaction. By this means, an aryl substituent was attached to the 2-position (50–62% yield). A succeeding cross-coupling with arylboronic acids 4 occurred at the 4-position of the intermediate 4-bromothiazoles 5 (76–97% yield)." @default.
- W2950470776 created "2019-06-27" @default.
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- W2950470776 date "2010-06-08" @default.
- W2950470776 modified "2023-09-24" @default.
- W2950470776 title "ChemInform Abstract: Synthesis of 2-(o-Hydroxyaryl)-4-arylthiazoles by Regioselective Pd(0)-Catalyzed Cross-Coupling." @default.
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- W2950470776 doi "https://doi.org/10.1002/chin.200023129" @default.
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