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- W2950470980 abstract "Mixed-ligand N,S-heterocy- clic carbene (NSHC) complexes, trans- (PdBr2A (NSHC = 3- benzyl- or 3-propyl-benzothiazolin-2-yl- idene), have been obtained from bridge-cleavage reactions of the dinu- clear complex, (PdAm-Br)BrA2, in pyridine at room temperature. Use of neutral N-bidentate donors (L = pyr- azine, 1,2-bis(4-pyridyl)ethane, 4,4'-bi- pyridine and trans-1,2-bis(4-pyridyl)- ethylene) yields the dinuclear spacer- bridged (Pd2Br4A2Am-L)) com- plexes. The X-ray single-crystal struc- tures of the pyridyl, bridging pyrazine and 1,2-bis(4-pyridyl)ethane complexes are reported. These air-stable com- plexes are active in the Suzuki- Miyaura coupling reactions of selected aryl bromides. The dinuclear com- plexes are generally more active than their mononuclear pyridyl analogues. The benzyl derivatives consistently out- perform the n-propyl counterparts." @default.
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- W2950470980 date "2009-01-06" @default.
- W2950470980 modified "2023-09-26" @default.
- W2950470980 title "ChemInform Abstract: Mono- and Dinuclear Palladium(II) N,S-Heterocyclic Carbene Complexes with N Spacers and Their Suzuki Coupling Activities." @default.
- W2950470980 cites W1967370753 @default.
- W2950470980 doi "https://doi.org/10.1002/chin.200901089" @default.
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