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- W2950478546 abstract "The new quaternary tantalum thiophosphate Rb4Ta4P4S24 was synthesized by reacting TaS2 with a molten polythiophosphate flux formed by Rb2S3, P2S5 and S at 773 K. The compound crystallizes in the monoclinic space group P21/n with a=13.849(3), b=17.647(4), c=15.900(3) Å, β=106.81(3)°, V=3720.1(13) Å3 and Z=4. The structure is composed of dimeric [Ta2S11] units which are linked by [PS4] tetrahedra to form 2∞[Ta4P4S24]4− layers. The significant structural difference of Rb4Ta4P4S24 to the known ternary and quaternary group 5 thiophosphates is the connection mode of the [M2Q11] units via [PS4] tetrahedra. In the title compound the [Ta2S11] moieties are bridged by two tetradentate and two tridentate [PS4] tetrahedra. Two types of cavities are observed in the 2∞[Ta4P4S24]4− layers with approximate diameters of 3.9·9.7 and 3.7·8.1 Å. The Rb+ ions are located between the layers above and below the cavities. The compound was characterized with MIR, Raman spectroscopy and UV–vis diffuse reflectance spectroscopy." @default.
- W2950478546 created "2019-06-27" @default.
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- W2950478546 date "2003-09-01" @default.
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- W2950478546 title "Synthesis, crystal structure and optical properties of the new layered quaternary tantalum thiophosphate Rb4Ta4P4S24 based on the interconnection of Ta2S11 units by PS4 tetrahedra" @default.
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- W2950478546 doi "https://doi.org/10.1016/s1293-2558(03)00155-9" @default.
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