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- W2950489711 abstract "Quinoline 1-oxides (1a-c) readily reacted with dimedone (2) and 1, 3-cyclohexanedione (10) in acetic anhydride or in dimethylformamide (DMF)-containing 1.2 eq of acetic anhydride to afford the corresponding 2-substituted quinolines (3a-c and 11a-c). The reaction of 3-bromoquinoline 1-oxide (1d) with 2 in DMF-acetic anhydride gave the 2-substituted quinoline (3d), whereas that in acetic anhydride alone afforded the enol acetate of 3d (3d'). The reactions of isoquinoline 2-oxide (5) with 2 and 10 similarly gave the 1-substituted isoquinolines (6 and 12). While pyridine 1-oxide (7) reacted with 2 to give the 2-substituted pyridine (8), the reaction with 10 produced 3-(2, 6-dioxocyclohexylidene)-2-(4-pyridyl) cyclohexanone (13)." @default.
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- W2950489711 date "1983-01-11" @default.
- W2950489711 modified "2023-09-27" @default.
- W2950489711 title "ChemInform Abstract: STUDIES ON TERTIARY AMINE OXIDES. LXXVI. REACTIONS OF AROMATIC N-OXIDES WITH 1,3-CYCLOHEXANEDIONES IN THE PRESENCE OF ACETIC ANHYDRIDE" @default.
- W2950489711 cites W2056893207 @default.
- W2950489711 doi "https://doi.org/10.1002/chin.198302189" @default.
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