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- W2950492050 abstract "A heterogeneous mono(phosphine)−Rh catalyst system silica-SMAP−Rh(OMe)(cod), where silica-SMAP stands for a caged, compact trialkylphosphine (SMAP) supported on silica gel, showed broad applicability toward the hydrogenation of hindered ketones. Doubly α-branched ketones such as diisopropyl ketone was hydrogenated under nearly atmospheric conditions. Di-tert-butyl ketone could be hydrogenated under more forcing conditions." @default.
- W2950492050 created "2019-06-27" @default.
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- W2950492050 date "2009-03-10" @default.
- W2950492050 modified "2023-10-05" @default.
- W2950492050 title "ChemInform Abstract: Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System." @default.
- W2950492050 cites W1976804736 @default.
- W2950492050 doi "https://doi.org/10.1002/chin.200910045" @default.
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