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- W2950497816 abstract "[reaction: see text] N-Acyl aldohydrazones I (R = CO(2)Et, alkyl, aryl, and furyl) efficiently trap the 1,3-dioxolanyl radical intermolecularly without external activation at temperatures as low as -78 degrees C. For alkyl aldohydrazones, good diastereoselectivities are obtained in the presence of InCl(3) at low temperature. Elaboration of the adducts (II) allows for the asymmetric synthesis of alpha-amino acid derivatives." @default.
- W2950497816 created "2019-06-27" @default.
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- W2950497816 date "2003-06-19" @default.
- W2950497816 modified "2023-09-27" @default.
- W2950497816 title "Diastereoselective Intermolecular Addition of the 1,3-Dioxolanyl Radical to <i>N</i>-Acyl Aldohydrazones. Asymmetric Synthesis of α-Amino Acid Derivatives" @default.
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- W2950497816 doi "https://doi.org/10.1021/ol034696n" @default.
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