FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950498743> ?p ?o ?g. }

• W2950498743 endingPage "6023" @default.
• W2950498743 startingPage "6008" @default.
• W2950498743 abstract "The lanthanide hypophosphite complexes Ln(H(2)PO(2))(3) (Ln = La, Pr, Nd) and Ln(H(2)PO(2))(3).H(2)O (Ln = La, Pr) crystallize in the space group P&onemacr; (No. 2), Z = 2. The lattice constants for La(H(2)PO(2))(3) are a = 6.7912(6) Å, b = 7.0801(8) Å, c = 8.863(1) Å, alpha = 82.64(1) degrees, beta = 74.43(1)( o), gamma = 71.91(1) degrees; for La(H(2)PO(2))(3).H(2)O, a = 7.2291(4) Å, b = 7.983(1) Å, c = 8.934(1) Å, alpha =110.57(1) degrees, beta = 98.26(1) degrees, gamma = 104.35(1) degrees. In both structures hypophosphite ions bridge adjacent 8-coordinate lanthanide ions to give infinite chains. Infrared and Raman spectra (300-20 K) are shown to be consistent with the crystallographic data, with 52 of the 54 fundamental hypophosphite modes of vibration assigned. The electronic spectra of the anhydrous compounds consist mainly of bands due to pure electronic electric dipole transitions. Two-center vibronic transitions observed in the (3)H(4) --> (1)D(2) spectrum of Pr(H(2)PO(2))(3) are not well-simulated by a model with dipole-dipole interaction terms between the two centers. The energy level scheme of Pr(3+) in Pr(H(2)PO(2))(3) was fitted to a model Hamiltonian for a C(2)(v)() site symmetry Pr(3+) ion, including configuration interaction of 4f(2) with 4f6p. Theoretical crystal field parameters were in reasonable agreement with those derived from the energy level fitting. The results highlight the C(2)(v)() (k even) and C(1) (k odd) distortions from the ideal D(4)(d)() antiprismal structure, which slightly modify the 4f(2) energy level scheme, and largely determine the spectral intensities in Pr(H(2)PO(2))(3), respectively. The derived energy level scheme of Nd(H(2)PO(2))(3) is similar to that for 8-coordinated Nd(3+) in NdCl(3).6H(2)O." @default.
• W2950498743 created "2019-06-27" @default.
• W2950498743 creator A5025981159 @default.
• W2950498743 creator A5040698159 @default.
• W2950498743 creator A5084853487 @default.
• W2950498743 date "1999-11-30" @default.
• W2950498743 modified "2023-09-25" @default.
• W2950498743 title "Synthesis, Structure, and Spectroscopy of Rare Earth Hypophosphites. 1. Anhydrous and Monohydrated Lanthanide Hypophosphites" @default.
• W2950498743 cites W1566787974 @default.
• W2950498743 cites W1639746141 @default.
• W2950498743 cites W1969494913 @default.
• W2950498743 cites W1970915986 @default.
• W2950498743 cites W1988988452 @default.
• W2950498743 cites W1989042575 @default.
• W2950498743 cites W1991308946 @default.
• W2950498743 cites W1994273000 @default.
• W2950498743 cites W1997253263 @default.
• W2950498743 cites W1998375219 @default.
• W2950498743 cites W1998942479 @default.
• W2950498743 cites W2003862344 @default.
• W2950498743 cites W2005310945 @default.
• W2950498743 cites W2009511315 @default.
• W2950498743 cites W2009762471 @default.
• W2950498743 cites W2012949406 @default.
• W2950498743 cites W2016932676 @default.
• W2950498743 cites W2017361774 @default.
• W2950498743 cites W2017863411 @default.
• W2950498743 cites W2018806479 @default.
• W2950498743 cites W2019118287 @default.
• W2950498743 cites W2023501829 @default.
• W2950498743 cites W2023656972 @default.
• W2950498743 cites W2025339149 @default.
• W2950498743 cites W2027688802 @default.
• W2950498743 cites W2029238491 @default.
• W2950498743 cites W2029878031 @default.
• W2950498743 cites W2030389313 @default.
• W2950498743 cites W2031420941 @default.
• W2950498743 cites W2036635873 @default.
• W2950498743 cites W2036818808 @default.
• W2950498743 cites W2037254453 @default.
• W2950498743 cites W2039778185 @default.
• W2950498743 cites W2041603559 @default.
• W2950498743 cites W2045689125 @default.
• W2950498743 cites W2050505120 @default.
• W2950498743 cites W2053036812 @default.
• W2950498743 cites W2054495138 @default.
• W2950498743 cites W2057585402 @default.
• W2950498743 cites W2058206324 @default.
• W2950498743 cites W2064521079 @default.
• W2950498743 cites W2067737184 @default.
• W2950498743 cites W2075501792 @default.
• W2950498743 cites W2090355876 @default.
• W2950498743 cites W2093972725 @default.
• W2950498743 cites W2095053857 @default.
• W2950498743 cites W2135999763 @default.
• W2950498743 cites W2148528852 @default.
• W2950498743 cites W2166583754 @default.
• W2950498743 cites W2323754398 @default.
• W2950498743 cites W2951252750 @default.
• W2950498743 cites W3004468574 @default.
• W2950498743 cites W4238138046 @default.
• W2950498743 doi "https://doi.org/10.1021/ic990187z" @default.
• W2950498743 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11671308" @default.
• W2950498743 hasPublicationYear "1999" @default.
• W2950498743 type Work @default.
• W2950498743 sameAs 2950498743 @default.
• W2950498743 citedByCount "25" @default.
• W2950498743 countsByYear W29504987432013 @default.
• W2950498743 countsByYear W29504987432014 @default.
• W2950498743 countsByYear W29504987432015 @default.
• W2950498743 countsByYear W29504987432016 @default.
• W2950498743 crossrefType "journal-article" @default.
• W2950498743 hasAuthorship W2950498743A5025981159 @default.
• W2950498743 hasAuthorship W2950498743A5040698159 @default.
• W2950498743 hasAuthorship W2950498743A5084853487 @default.
• W2950498743 hasConcept C115624301 @default.
• W2950498743 hasConcept C120665830 @default.
• W2950498743 hasConcept C121332964 @default.
• W2950498743 hasConcept C145148216 @default.
• W2950498743 hasConcept C153642686 @default.
• W2950498743 hasConcept C178790620 @default.
• W2950498743 hasConcept C185592680 @default.
• W2950498743 hasConcept C201770740 @default.
• W2950498743 hasConcept C40003534 @default.
• W2950498743 hasConcept C71240020 @default.
• W2950498743 hasConcept C8010536 @default.
• W2950498743 hasConceptScore W2950498743C115624301 @default.
• W2950498743 hasConceptScore W2950498743C120665830 @default.
• W2950498743 hasConceptScore W2950498743C121332964 @default.
• W2950498743 hasConceptScore W2950498743C145148216 @default.
• W2950498743 hasConceptScore W2950498743C153642686 @default.
• W2950498743 hasConceptScore W2950498743C178790620 @default.
• W2950498743 hasConceptScore W2950498743C185592680 @default.
• W2950498743 hasConceptScore W2950498743C201770740 @default.
• W2950498743 hasConceptScore W2950498743C40003534 @default.
• W2950498743 hasConceptScore W2950498743C71240020 @default.
• W2950498743 hasConceptScore W2950498743C8010536 @default.
• W2950498743 hasIssue "26" @default.

• next