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- W2950500503 abstract "A smooth and efficient oxidation of isonitriles to isocyanates by sulfoxides is catalyzed by trifluoroacetic anhydride. With use of DMSO as the oxidant and 5 mol·% TFAA (dichloromethane, −60 to 0 °C), the process is complete in a few minutes, forming dimethyl sulfide as the only byproduct. The newly formed isocyanates may be used directly or isolated in high purity by solvent evaporation." @default.
- W2950500503 created "2019-06-27" @default.
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- W2950500503 date "2011-08-04" @default.
- W2950500503 modified "2023-09-25" @default.
- W2950500503 title "ChemInform Abstract: Trifluoroacetic Anhydride-Catalyzed Oxidation of Isonitriles by DMSO: A Rapid, Convenient Synthesis of Isocyanates." @default.
- W2950500503 cites W2038903704 @default.
- W2950500503 doi "https://doi.org/10.1002/chin.201135065" @default.
- W2950500503 hasPublicationYear "2011" @default.
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