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- W2950504531 abstract "An efficient and cheap synthetic approach to functionalized exo-methylene cyclopentanes has been developed from α-disubstituted formyl-alkynes by merging amine catalysis with the indium activation of alkynes. We uncovered the crucial role of the amine cocatalyst and the development of a new cooperative catalytic system allowed the cyclization of a broad range of substrates. A mechanistic study was realized in order to rationalize the determining influence of the amine cocatalyst." @default.
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- W2950504531 date "2010-11-05" @default.
- W2950504531 modified "2023-09-23" @default.
- W2950504531 title "InCl<sub>3</sub>/CyNH<sub>2</sub> Cocatalyzed Carbocyclization Reaction: An Entry to α-Disubstituted <i>exo</i>-Methylene Cyclopentanes" @default.
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- W2950504531 doi "https://doi.org/10.1021/jo1018552" @default.
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