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- W2950508169 abstract "Abstract The optically active β-amino alcohol (1 R ,3 R ,5 R )-3-(diphenylhydroxymethyl)-2-azabicyclo[3.3.0]octane (1 R ,3 R ,5 R )- 1 derived from a bicyclic proline analogue catalyzes the enantioselective addition of diethylzinc to various aldehydes. The resulting chiral secondary alcohols are obtained in high optical yields up to 100 % under mild reaction conditions. The bicyclic catalyst gives much better results than the corresponding ( S )-proline derivative ( S )- 4 ." @default.
- W2950508169 created "2019-06-27" @default.
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- W2950508169 date "2010-08-20" @default.
- W2950508169 modified "2023-09-26" @default.
- W2950508169 title "ChemInform Abstract: Catalytic Enantioselective Addition of Diethylzinc to Aldehydes: Application of a New Bicyclic Catalyst." @default.
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- W2950508169 doi "https://doi.org/10.1002/chin.199330114" @default.
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