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- W2950512955 abstract "A new oxidation reaction based on two simple catalysts, namely, alloxan and a CuI salt, is highly effective for the aerobic oxidation and oxidative cross-coupling of amines. The reaction is operationally simple, reaction atmospheres enriched in dioxygen are obviated, and neither catalyst component requires prior synthesis. Mechanistic investigations have been performed and point towards a complex reaction manifold with evidence that supports a catalytic cycle that does not proceed through a quinone-imine step. Additionally, this dual catalyst system is efficient to effect diimide-mediated hydrogenation reactions of alkenes and alkynes, a transformation that has not been reported previously in the context of quinone catalyst systems." @default.
- W2950512955 created "2019-06-27" @default.
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- W2950512955 date "2016-06-01" @default.
- W2950512955 modified "2023-09-26" @default.
- W2950512955 title "ChemInform Abstract: Symbiotic Transition-Metal and Organocatalysis for Catalytic Ambient Amine Oxidation and Alkene Reduction Reactions." @default.
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- W2950512955 doi "https://doi.org/10.1002/chin.201625022" @default.
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