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- W2950522024 abstract "The para-substituted diphenylzirconocenes [(t-BuCp)2Zr(p-C6H4R)2; R = Br, NMe2] (A) were easily obtained from the reaction of the appropriate organolithium reagent with bis(t-butylcyclopentadienyl)zirconium dichloride. Elimination of bromobenzene or N,N-dimethylaminobenzene from A by slight heating led to arynezirconocenes into which were inserted two equivalents of elementary chalcogens. As a result dichalcogenated zirconacycles [(t-BuCp)2ZrY2C6H3R; Y = S, Se] (B) were obtained. Complexes B constitute useful potential synthons in organic synthesis and a large family of new functionalized dichalcogenated benzenic compounds was prepared by reacting electrophiles.The structure of complexes B as well as related benzenic derivatives has been confirmed by microanalysis, 1H NMR and mass spectrometry." @default.
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- W2950522024 date "2010-08-21" @default.
- W2950522024 modified "2023-09-25" @default.
- W2950522024 title "ChemInform Abstract: Formation of Arynezirconocenes from Substituted Diaryl Bis(t- butylcyclopentadienyl)zirconium: Application to the Synthesis of New Functionalized ortho-Dichalcogenobenzene Compounds." @default.
- W2950522024 cites W2007280534 @default.
- W2950522024 doi "https://doi.org/10.1002/chin.199248242" @default.
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