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- W2950522077 abstract "Anopterine (1), a major alkaloid from leaf and bark of Anoptevus macleayanus F. Muell. and bark of Anoptevus glandulosus Labill., has an unusual ent-kaurenoid skeleton with a C20-C14 linkage. Hydrolysis of anopterine gives anopteryl alcohol (5), C21H31N05, and two equivalents of tiglic acid. The chemical reactions of anopterine and anopteryl alcohol have been studied in detail, and a number of acetylation products and oxidation products have been obtained. Oxidation of anopteryl alcohol with potassium ferricyanide has given an unusual product (14) which has a C20,C12-oxide bridge and a C5,C6-epoxide group." @default.
- W2950522077 created "2019-06-27" @default.
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- W2950522077 date "1976-11-09" @default.
- W2950522077 modified "2023-09-24" @default.
- W2950522077 title "ChemInform Abstract: NEW ALKALOIDS OF THE ENT-KAURENE TYPE FROM ANOPTERUS SPECIES (ESCALLONIACEAE). I. THE STRUCTURE AND REACTIONS OF ANOPTERINE" @default.
- W2950522077 cites W2039300613 @default.
- W2950522077 doi "https://doi.org/10.1002/chin.197645385" @default.
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