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- W2950527562 abstract "A method for direct synthesis of tetrasubstituted fluoroarenes via nickel-catalyzed [2+2+2] cycloaddition is presented. The reaction combines one molecule of 1,1-difluoroethylene with two molecules of alkynes and involves sequential cleavage of the CF and CH bonds in difluoroethylene. The catalytic cycle is established by reduction of the intermediary NiII fluoride with a triethylborane-based borate." @default.
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- W2950527562 date "2016-01-01" @default.
- W2950527562 modified "2023-09-27" @default.
- W2950527562 title "ChemInform Abstract: Ni-Catalyzed Synthesis of Fluoroarenes via [2 + 2 + 2] Cycloaddition Involving α-Fluorine Elimination." @default.
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- W2950527562 doi "https://doi.org/10.1002/chin.201606103" @default.
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