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- W2950532090 abstract "New generation of nitrile oxides by treatment of hydroximoyl chlorides with organometallics is reported. Their cycloadditions to the allyl alcohols bearing a chiral center at the 1-position proceed in a syn-selective manner, providing the first example of stereocontrol of 1,3-dipolar cycloaddition by the aid of metal chelation." @default.
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- W2950532090 date "1991-10-01" @default.
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- W2950532090 title "Generation of nitrile oxides through O-metalation of hydroximoyl chlorides. Chelation-controlled syn-selective cycloaddition of nitrile oxides to α-substituted allyl alcohols" @default.
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- W2950532090 doi "https://doi.org/10.1016/0040-4039(91)80171-2" @default.
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